MS 899 - Beginning Mechanism Practice

MS 899 - Beginning Mechanism Practice

Textbook and Chapters: Carey and Giuliano 8th Ed. (2010), Chapters 4, 5

Keywords: carbocation rearrangement, free radical halogenation, mechanism

Description: Practice mechanisms from the first half of Fall semester orgo. Dehydration (E1), substitution with carbocation rearrangement (SN1), and free-radical bromination.

Total Problems: 3

  1. Problem # 321
     

    Using curved arrows, draw a mechanism for the SN1 reaction shown below.

     

  2. Problem # 322
     

    Using curved arrows, draw a mechanism for the SN1 reaction shown below.

  3. Problem # 324
     

    Using curved hooks, draw a mechanism for the free radical bromination  reaction shown below.